Product ID:FORMULA 100 INSECTICIDE
MSDS Date:06/01/1987
FSC:6840
NIIN:00N010102
MSDS Number: BHVBC

STATE CHEMICAL MANUFACTURING CO.

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

MALATHION (SARA III)

CAS: 121-75-5

RTECS: WM8400000

Fraction By Weight: 3.0%

OSHA PEL S, 15 MG/M3

ACGIH TLV: S, 10 MG/M3; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PYRETHRUM (SARA III)

CAS: 8003-34-7

RTECS: UR4200000

Fraction By Weight: 0.05%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

PIPERONYL BUTOXIDE

CAS: 51-03-6

RTECS: XS5805000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

PETROLEUM DISTILLATE

CAS: 68476-34-6

Fraction By Weight: 96.825%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL OR FATAL IF
SWALLOWED.CHOLINESTERASE INHIBITOR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:IRRITANT.SKIN:PYRETHRUM CAN CAUSE SKIN
RASH PARTICULARLY ON MOIST AREAS OF THE SKIN.HARMFUL IF ABSORBED
THROUGH THE SKIN.INGESTION:HARMFUL OR FATAL IF
SWALLOWED.INHALATION:TIGHTNESS OF CHEST,WHEE ZING,SMALL
PUPILS,BLURRING OF VISION,RUNNY NOSE,HEADACHE,WATERING OF THE
MOUTH.HARMFUL IF INHALED.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH IMMED W/ PLENTY OF COOL WATERR FOR AT LEAST 15
MIN.GET MED ATTN IMMED.SKIN:IMMED WASH THE SKIN W/ SOAP & LGE AMTS
OF H*2O.REMOVE CONTAM CLTHG & WASH BEFORE REUSE.CONTACT AN
MD.INGEST:DO NOT INDUCE VOMIT DUE TO ASPIR HAZ.CALL MD
IMMED.INHAL:REMOVE TO FRESH AIR.GIVE ARTF RESP IF NEEDED.CALL MD
IMMED.NOTE:PRLNG/RPTD CONTACT W/ MALATHION MAY CAUSE CHOLINESTERASE
INHIBITION.GIVE ATROPINE.

Flash Point Method:TCC
Flash Point:148F,64.4C
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:CARBON DIOXIDE,FOAM,OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .FIREFIGHTERS SHOULD BE PROTECTED FROM FUMES
GIVEN OFF BY WEARING A SCBA.
Unusual Fire/Explosion Hazard:HAZARDOUS DECOMPOSITION PRODUCTS MAY
INCLUDE PHOSPHOROUS TRIOXIDE,SULFATES ,SULFUR DIOXIDE,PHOSPHORIC
ACID,AND CARBON MONOXIDE.

Spill Release Procedures:IF 55 GALLONS OF THE MATERIAL IS
SPILLED,CONTACT THE APPROPRIATE AGENCIES CONCERNING THE RELEASE OF
A REPORTABLE QUANTITY OF MALATHION.SMALLER VOLUMES CAN BE CLEANED
UP AND DISPOSED OF PROPERLY USING LABEL DISPOSAL DIRECTIONS.
Neutralizing Agent:N/K

Handling and Storage Precautions:DO NOT SPRAY,POUR,SPILL,OR STORE NEAR
HEAT,SPARKS OR OPEN FLAME.DO NOT APPLY TO ANY FOOD,FEED,FORAGE
CROPS.KEEP CNTRS CLOSED WHEN NOT IN USE (SEE SUP)
Other Precautions:FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY.KEEP OUT OF
REACH OF CHILDREN.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH STATION OR CLEAN WATER SOURCE IN
CASE OF ACCIDENTAL SPLASHING.RUBBER FOOTWEAR AND OTHER IMPERVIOUS
CLOTHING.
Work Hygienic Practices:N/K
Supplemental Safety and Health
HNDLG/STOR PREC:DO NOT REUSE CONTAINERS FOR ANY PURPOSE.DO NOT USE
CUTTING TORCH OR WELD EMPTY DRUMS.DO NOT USE ON PETS.DO NOT USE IN
DAIRY BARNS OR DAIRY ANIMALS/LIVESTOCK INTENDED FOR SLAUGHTER.FOLL
OW ALL PRECAUTIONS ON LABEL.USE ONLY ACCORDING TO LABEL
INSTRUCTIONS.% VOLAT:100 BY WEIGHT.

Boiling Pt:B.P. Text:375-525F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:0.854 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:NEGLIGIBLE
Appearance and Odor:A CLEAR AMBER LIQUID WITH A PETROLEUM ODOR.
Percent Volatiles by Volume:SUPP

Stability Indicator/Materials to Avoid:YES
CARBARYL,ARAMITE,ENDRIN,SULPHENONE,TOXAPHENE,DODINE,FERBAM,THIRAM,ZINEB
,ZIRAM,STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT,SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:PHOSPHOROUS TRIOXIDE,SULFATES,SULFUR
DIOXIDE,PHOSPHORIC ACID,AND CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .OPEN DUMPING PROHIBITED.FOLLOW
LABEL DIRECTIONS.

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